ENSCR-recherche-OMC-Marc Mauduit

Dr. Marc Mauduit (CV)


Marc Mauduit obtained his Ph.D degree in 1999 from the University of Paris-Sud Orsay in France under the guidance of Prof. Y. Langlois. After working as postdoctoral fellow with Prof. S. Hanessian at Montreal University in Canada, he joined the Ecole Nationale Supérieure de Chimie de Rennes (UMR CNRS 6226 « Institut des Sciences Chimiques de Rennes ») in 2001 as Researcher Fellow at CNRS. In 2010, he was appointed Reseacher Director at CNRS. His research interest mainly focuses on organometallic chemistry, including olefin metathesis and enantioselective catalysis involving newly designed chiral ligands (N-heterocyclic carbenes and Phosphino-Schiff bases).

ENSCR-recherche-OMC-Olivier Basle

Dr. Olivier Baslé (CV)


Olivier Baslé completed his Master degree under the supervision of Prof. P.H Dixneuf at the university of Rennes in 2006 and obtained his PhD degree in 2009 at McGill University under the guidance of Prof. C.-J. Li. After postdoctoral studies with Prof. J. Rodriguez and T. Constantieux in Marseille and Dr. D. Bourrisou in Toulouse, he was appointed Chargé de Recherche (CNRS) at Ecole Nationale Supérieure de Chimie de Rennes in 2011. In 2018, he joined the CNRS Laboratory of Coordination Chemistry (LCC) in Toulouse. His research program focuses on the development of selective catalytic transformations using N-Heterocyclic Carbene-metal complexes. His research interests include organic synthesis, organometallic chemistry and homogeneous catalysis.



Dr. Christophe Crévisy (CV)


Christophe Crévisy received his PhD degree in 1992 from the University of Orléans. His PhD studies on the synthesis of antitumor enediynes were carried out under the direction of Dr. Jean-Marie Beau. From 1992 to 1993, he did a postdoctoral work with Pr. Pierre Deslongchamps at the University of Sherbrooke (Canada). Since 1994, he has been a senior lecturer at the Ecole Nationale Supérieure de Chimie de Rennes. He received his “Habilitation à Diriger les Recherches” degree in 2004. His main research interests are the development of new chiral ligands dedicated to asymmetric catalysis of reactions such as conjugated additions or allylic alkylation, the application of olefin metathesis to the valorisation of raw materials isolated from renewable resources and the development of new anti-tumor N-Heterocyclic Carbene/metal complexes.


Sophie Colombel-Rouen (CV)


Sophie Colombel-Rouen received her Ph.D. degree in 2012 from the National Institute of Applied Sciences (INSA) in Rouen under the supervision of Professor Xavier Pannecoucke and Dr. Eric Leclerc. Her Ph.D. studies were on the synthesis of difluorinated α-C- galactosylceramides and the assessment of their immunoregulation properties for the treatment of systemic autoimmune diseases. After postdoctoral work with Professor Thierry Benvegnu at Ecole Nationale Supérieure de Chimie de Rennes, she was appointed Engineer at ENSCR. Her main mission is to support the OMC (Organometallics, Materials & Catalysis) team in their research and to validate programs through organic synthesis.


Dr. Daniel Müller



“The Biomass Valorization by Olefin Metathesis: A Real Challenge for Tomorrow.” H. Olivier-Bourbigou, Y. Raoul, P. Piot, C. Crévisy, O. Baslé, M. Mauduit, Actualité Chimique 2018, 432, 18-28.

“Directed Ortho C-H Borylation Catalyzed Using Cp*Rh(III)-NHC Complexes.” J. Thongpaen, T. E. Schmid, L. Toupet, V. Dorcet, M. Mauduit, O. Baslé, Chem. Commun. 2018, 54, 8202-8205.


“A Versatile and Highly Z-Selective Olefin Metathesis Ruthenium Catalyst Based on a Readily Acessible N-Heterocyclic Carbene.” A. Dumas, R. Tarrieu, T. Vives, T. Roisnel, V. Dorcet, O. Baslé, M. Mauduit. ACS. Catal. 2018, 8, 3257-3262.

“Synthesis and Application of Stereoretentive Ruthenium Catalyst on the Basis of the M7 and the Ru-Benzylidene-Oxazinone Design.” A. Dumas, D. S. Müller, I. Curbet, L. Toupet, M. Rouen, O. Baslé, M. Mauduit. Organometallics 2018, 37, 829-834.

“Bleaching Earths as Powerful Additives for Ru-Catalyzed Self-Metathesis of Non-Refined Methyl Oleate at Pilot Scale.” J. Allard, I. Curbet, G. Chollet, F. Tripoteau, S. Sambou, F. Caijo, Y. Raoul, C. Crévisy, O. Baslé, M. Mauduit. Chem. Eur. J. 2017, 23,12729-12734.

“Readily Accessible Unsymmetrical Unsaturated 2,6-Diisopropylphenyl N-Heterocyclic Carbene Ligands. Applications in Enantioselective Catalysis.” R. Tarrieu, A. Dumas, J. Thongpaen, T. Vives, T. Roisnel, V. Dorcet, C. Crévisy, O. Baslé, M. Mauduit. J. Org. Chem. 2017, 82, 1880-1887.


“From Environmentally Reusable Ionic-Tagged Ruthenium-Based Complexes to Industrially Relevant Homogeneous Catalysts: Toward a Sustainable Olefin Metathesis.”  T. E. Shmid, A. Dumas, S. Colombel-Rouen, C. Crévisy, O. Baslé, M. Mauduit. Synlett. 2017, 28, 773-798

web only. Editor: David Smith JEM: Esther

“Selective Metathesis of α-Olefins from Bio-Sourced Fischer–Tropsch Feeds.” M. Rouen, P. Queval, E. Borré, L. Falivene, A. Poater, M. Berthod, F. Hugues, L. Cavallo, O. Baslé, H. Olivier-Bourbigou, M. Mauduit. ACS catal. 2016, 6, 7970-7976

ASC 2016

“Copper-Catalyzed Asymmetric Conjugate Addition of Dimethylzinc to Acyl-N-methylimidazole Michael Acceptors: Scope, Limitations and Iterative Reactions.” S. Drissi-Amraoui, T. E. Schmid, J. Lauberteaux, C. Crévisy, O. Baslé, R. Marcia de Figueiredo, S. Halbert, H. Gérard, M. Mauduit, J.-M. Campagne. Adv. Synth. Catal. 2016, 358, 2519-2540.

ENSCR-recherche-OMC-ASC 216_GA
chemcom 2016

“Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands.” N. Hellou, C. Jahier-Diallo, O. Baslé, M. Srebro-Hooper, L. Toupet, T. Roisnel, E. Caytan, C. Roussel, N. Vanthuyne, J. Autschbach, M. Mauduit, J. Crassous. Chem. Commun. 2016, 52, 9243-9246.

ENSCR-recherche-OMC-chemcom 2016_GA
ENSCR-recherche-OMC-Angew 2015

“Copper-Catalyzed Asymmetric Conjugate Addition of Dimethylzinc to Acyl-N-methylimidazole Michael Acceptors : a Powerful Synthetic Platform.” S. Drissi-Amraoui, M. S. T. Morin, C. Crévisy, O. Baslé, R. Marcia de Figueiredo, M. Mauduit, J.-M. Campagne. Angew. Chem. Int. Ed. 2015, 54, 11830-11834.

Beilstein JOC 2015

“Latent Ruthenium-Indenylidene Catalyst bearing a N-Heterocyclic Carbene and a Bidentate Picolinate.” T. Shmid, F. Modicom, A. Dumas, E. Borré L. Toupet, O.Baslé, M. Mauduit, Belstein J. Org. Chem. 2015, 11, 1541-1546.

ENSCR-recherche-OMC-BJOC 2015_GA
ENSCR-recherche-OMC-Synthesis 2015

“Efficiency of Industrially Relevant Atropisomeric Diphosphines in Copper-Catalyzed 1,4-Asymmetric Conjugate Addition of Dialkylzincs to Cyclic or Acyclic Enones or Dienones” M. S. T. Morin, T. Vives, O. Baslé, C. Crévisy, V. Ratovelomanana-Vidal, M. Mauduit. Synthesis, 2015, 47, 2570-2577.

ENSCR-recherche-OMC-Synthesis 2015_GA
ENSCR-recherche-OMC-Chemistry 2015_U2

“Multicomponent Synthesis of Chiral Bidentate Unsymmetrical Unsaturated N- Heterocyclic Carbenes: Copper-Catalyzed Asymmetric C-C Bond Formation.” C. Jahier-Diallo, M. S. T. Morin, P. Queval, M. Rouen, I. Artur, P. Querard, L. Toupet, C. Crévisy, O. Baslé, M. Mauduit. Chem. Eur. J. 2015, 21, 993-997.

ENSCR-recherche-OMC-CEJ 2015_GA
ENSCR-recherche-OMC-Chemistry 2014 “Cationic Bis N-Heterocyclic Carbene Ruthenium Complex: Structure and Application as Latent Catalyst in Olefin Metathesis.” M. Rouen, P. Queval, L. Falivene, J. Allard, L. Toupet, C. Crévisy, F. Caijo, O. Baslé, L. Cavallo, M. Mauduit. Chem. Eur. J. 2014, 20, 13716-13721. ENSCR-recherche-OMC-CEJ 2014_GA
Angew 2013 Multicomponent Synthesis of (a)chiral Unsymmetrical Unsaturated N-Heterocyclic Carbene (U2-NHC) Precursors; and Their Related Transition-Metal Complexes P. Queval, C. Jahier, M. Rouen, I. Artur, J.-C. Legeay, L. Falivene, L. Toupet, C. Crévisy, L. Cavallo, O. Baslé, M. Mauduit. Angew. Chem. Int. Ed. 2013, 52, 14103-14107.
ENSCR-recherche-OMC-Angew 2013_GA
Chemistry 2013 ACA

« Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex. Extension to asymmetric sequential 1,6/1,4 Conjugate Addition. » M. Magrez-Chiquet, M. S. T. Morin, J. Wencel-Delord, S. Drissi Amraoui, O. Baslé, A. Alexakis, C. Crévisy, M. Mauduit. Chem. Eur. J., 2013, 19, 13663. (Synfacts 2014, 10, 0042).

ENSCR-recherche-OMC-CEJ 2013_ACA_GA

« Synergic Effects Between N-Heterocyclic Carbene and Chelating-Benzylidene-Ether Ligands Towards the Initiation Step of Hoveyda-Grubbs Type Ru-Complexes. » D. J. Nelson, P. Queval, M. Rouen, M. Magrez, F. Caijo, E. Borré, I. Laurent, C. Crévisy, O. Baslé, M. Mauduit, J. M. Percy. ACS Catalysis, 2013, 3, 259-264

graphical abstract
cat sc tech 2013

“Screening of a Selection of Commercially Available Homogeneous Ru-Catalysts in Valuable Olefin Metathesis Transformations.”  F. Caijo, F. Tripoteau, A. Bellec, C. Crévisy, O. Baslé, M. Mauduit, O. Briel.  Catal. Sci. Technol., 2013, 3, 429-435

ENSCR-recherche-OMC-CST 2013_GA
Chemistry 2013 AAA

“Bidentate Hydroxyalkyl-NHC Ligands for Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Grignard Reagents.” M. Magrez, Y. Le Guen, O. Baslé, C. Crévisy, M. Mauduit, Chem. Eur. J., 2013, 19, 1199-1203. (Synfacts 2013, 4, 0427)

ENSCR-recherche-OMC-CEJ 2013_AAA_GA


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